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addition reaction : ウィキペディア英語版
addition reaction

An addition reaction, in organic chemistry, is in its simplest terms an organic reaction where two or more molecules combine to form a larger one (the adduct).

Addition reactions are limited to chemical compounds that have multiple bonds, such as molecules with carbon-carbon double bonds (alkenes), or with triple bonds (alkynes). Molecules containing carbon—hetero double bonds like carbonyl (C=O) groups, or imine (C=N) groups, can undergo addition as they too have double bond character.
An addition reaction is the opposite of an elimination reaction. For instance the hydration reaction of an alkene and the dehydration of an alcohol are addition-elimination pairs.
There are two main types of polar addition reactions: electrophilic addition and nucleophilic addition. Two non-polar addition reaction exists as well called free radical addition and cycloadditions. Addition reactions are also encountered in polymerizations and called addition polymerization.
==Addition-elimination reaction==
In the related addition-elimination reaction an addition reaction is followed by an elimination reaction. In the majority of reactions it involves addition of nucleophiles to carbonyl compounds in what is called nucleophilic acyl substitution.〔''Reaction-Map of Organic Chemistry'' Murov, Steven. J. Chem. Educ. 2007, 84, 1224 (Abstract )〕

Other addition-elimination reactions are the reaction of an aliphatic amine to an imine and an aromatic amine to a Schiff base in alkylimino-de-oxo-bisubstitution. The hydrolysis of nitriles to carboxylic acids is also a form of addition-elimination.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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